Structural and Vibrational Study of (NH4)3H(SO4)1.42(SeO4)0.58 Mixed Crystals
Identifieur interne : 001A87 ( Main/Exploration ); précédent : 001A86; suivant : 001A88Structural and Vibrational Study of (NH4)3H(SO4)1.42(SeO4)0.58 Mixed Crystals
Auteurs : M. Gargouri ; R. Ben Hassen [Tunisie] ; T. Mhiri [Tunisie] ; A. Daoud [Tunisie]Source :
- physica status solidi (b) [ 0370-1972 ] ; 1998-04.
English descriptors
- Teeft :
Abstract
At room temperature (T = 293(2) K) (NH4)3H(SO4)1.42(SeO4)0.58 (NHSSe) Mm = 274.34 g possesses a monoclinic structure with space group Cc. The unit cell parameters are: a = 15.564(6) Å, b = 5.9180(6) Å, c = 10.275(2) Å, β = 102.09(2)°, V = 925.4(4) Åü3, Z = 4, Dx = 1.97 g/cm3. The structure was determined with R = 0.0529 and wR2 = 0.1373 for 826 observed reflections. The Raman and infrared spectra at room temperature were investigated in the frequency ranges 10 to 1300 cm—1and 400 to 1600 cm—1, respectively. The assignment of most of the bands is given. We note for this compound two kinds of disorder to be expected: a statistical or dynamic disorder of the acidic proton O–H–O hydrogen bond and another one which is connected with a reorientational motion of NH+4 ions.
Url:
DOI: 10.1002/(SICI)1521-3951(199804)206:2<535::AID-PSSB535>3.0.CO;2-N
Affiliations:
Links toward previous steps (curation, corpus...)
- to stream Istex, to step Corpus: 000048
- to stream Istex, to step Curation: 000048
- to stream Istex, to step Checkpoint: 000882
- to stream Main, to step Merge: 001B42
- to stream Main, to step Curation: 001A87
Le document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">Structural and Vibrational Study of (NH4)3H(SO4)1.42(SeO4)0.58 Mixed Crystals</title><author><name sortKey="Gargouri, M" sort="Gargouri, M" uniqKey="Gargouri M" first="M." last="Gargouri">M. Gargouri</name></author><author><name sortKey="Ben Hassen, R" sort="Ben Hassen, R" uniqKey="Ben Hassen R" first="R." last="Ben Hassen">R. Ben Hassen</name></author><author><name sortKey="Mhiri, T" sort="Mhiri, T" uniqKey="Mhiri T" first="T." last="Mhiri">T. Mhiri</name></author><author><name sortKey="Daoud, A" sort="Daoud, A" uniqKey="Daoud A" first="A." last="Daoud">A. Daoud</name></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:7483FD3906057600BEBA44D680708AFBAE28752C</idno><date when="1998" year="1998">1998</date><idno type="doi">10.1002/(SICI)1521-3951(199804)206:2<535::AID-PSSB535>3.0.CO;2-N</idno><idno type="url">https://api.istex.fr/ark:/67375/WNG-NRHNVFRQ-8/fulltext.pdf</idno><idno type="wicri:Area/Istex/Corpus">000048</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">000048</idno><idno type="wicri:Area/Istex/Curation">000048</idno><idno type="wicri:Area/Istex/Checkpoint">000882</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Checkpoint">000882</idno><idno type="wicri:doubleKey">0370-1972:1998:Gargouri M:structural:and:vibrational</idno><idno type="wicri:Area/Main/Merge">001B42</idno><idno type="wicri:Area/Main/Curation">001A87</idno><idno type="wicri:Area/Main/Exploration">001A87</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a" type="main">Structural and Vibrational Study of (NH4)3H(SO4)1.42(SeO4)0.58 Mixed Crystals</title><author><name sortKey="Gargouri, M" sort="Gargouri, M" uniqKey="Gargouri M" first="M." last="Gargouri">M. Gargouri</name></author><author><name sortKey="Ben Hassen, R" sort="Ben Hassen, R" uniqKey="Ben Hassen R" first="R." last="Ben Hassen">R. Ben Hassen</name><affiliation wicri:level="1"><country xml:lang="fr">Tunisie</country><wicri:regionArea>Laboratoire de l'Etat Solide (LES), Faculté des Sciences de Sfax, route de soukra, 3038 Sfax</wicri:regionArea><wicri:noRegion>3038 Sfax</wicri:noRegion></affiliation></author><author><name sortKey="Mhiri, T" sort="Mhiri, T" uniqKey="Mhiri T" first="T." last="Mhiri">T. Mhiri</name><affiliation wicri:level="1"><country xml:lang="fr">Tunisie</country><wicri:regionArea>Laboratoire de l'Etat Solide (LES), Faculté des Sciences de Sfax, route de soukra, 3038 Sfax</wicri:regionArea><wicri:noRegion>3038 Sfax</wicri:noRegion></affiliation></author><author><name sortKey="Daoud, A" sort="Daoud, A" uniqKey="Daoud A" first="A." last="Daoud">A. Daoud</name><affiliation wicri:level="1"><country xml:lang="fr">Tunisie</country><wicri:regionArea>Laboratoire de l'Etat Solide (LES), Faculté des Sciences de Sfax, route de soukra, 3038 Sfax</wicri:regionArea><wicri:noRegion>3038 Sfax</wicri:noRegion></affiliation></author></analytic><monogr></monogr><series><title level="j" type="main">physica status solidi (b)</title><title level="j" type="alt">PHYSICA STATUS SOLIDI B</title><idno type="ISSN">0370-1972</idno><idno type="eISSN">1521-3951</idno><imprint><biblScope unit="vol">206</biblScope><biblScope unit="issue">2</biblScope><biblScope unit="page" from="535">535</biblScope><biblScope unit="page" to="544">544</biblScope><biblScope unit="page-count">10</biblScope><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Berlin</pubPlace><date type="published" when="1998-04">1998-04</date></imprint><idno type="ISSN">0370-1972</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0370-1972</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="Teeft" xml:lang="en"><term>Hxsv</term><term>Hxsv wixed</term><term>Ionsf</term><term>Ixrp</term><term>Mmonium</term><term>Ngles</term><term>Ompounds</term><term>Onds</term><term>Pigf</term><term>Solid solutionf</term><term>Ssigned</term><term>Tudy</term><term>Whirid</term><term>Wixed</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="de">At room temperature (T = 293(2) K) (NH4)3H(SO4)1.42(SeO4)0.58 (NHSSe) Mm = 274.34 g possesses a monoclinic structure with space group Cc. The unit cell parameters are: a = 15.564(6) Å, b = 5.9180(6) Å, c = 10.275(2) Å, β = 102.09(2)°, V = 925.4(4) Åü3, Z = 4, Dx = 1.97 g/cm3. The structure was determined with R = 0.0529 and wR2 = 0.1373 for 826 observed reflections. The Raman and infrared spectra at room temperature were investigated in the frequency ranges 10 to 1300 cm—1and 400 to 1600 cm—1, respectively. The assignment of most of the bands is given. We note for this compound two kinds of disorder to be expected: a statistical or dynamic disorder of the acidic proton O–H–O hydrogen bond and another one which is connected with a reorientational motion of NH+4 ions.</div></front></TEI><affiliations><list><country><li>Tunisie</li></country></list><tree><noCountry><name sortKey="Gargouri, M" sort="Gargouri, M" uniqKey="Gargouri M" first="M." last="Gargouri">M. Gargouri</name></noCountry><country name="Tunisie"><noRegion><name sortKey="Ben Hassen, R" sort="Ben Hassen, R" uniqKey="Ben Hassen R" first="R." last="Ben Hassen">R. Ben Hassen</name></noRegion><name sortKey="Daoud, A" sort="Daoud, A" uniqKey="Daoud A" first="A." last="Daoud">A. Daoud</name><name sortKey="Mhiri, T" sort="Mhiri, T" uniqKey="Mhiri T" first="T." last="Mhiri">T. Mhiri</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Sante/explor/H2N2V1/Data/Main/Exploration
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 001A87 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 001A87 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Sante
|area= H2N2V1
|flux= Main
|étape= Exploration
|type= RBID
|clé= ISTEX:7483FD3906057600BEBA44D680708AFBAE28752C
|texte= Structural and Vibrational Study of (NH4)3H(SO4)1.42(SeO4)0.58 Mixed Crystals
}}
| This area was generated with Dilib version V0.6.33. |  |